2,616 research outputs found

    Optical conductivity of alpha-Mn

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    The optical constants were measured at room temperature in the photon-energy range 0.6 to 6.5 eV on evaporated thin films. Evaporation conditions were chosen that gave the alpha-Mn crystal structure with reasonably large grains. The optical conductivity was separated into intraband and interband contributions by fitting to the Drude formula at low energies. The results are anomalous in comparison to other 3d transition metals. The free-electron lifetime is exceptionally sort (in agreement with the large dc resistivity of Mn), and the interband transitions seem unusually weak at the lower energies. Possible explanations related to the complicated crystal structure of alpha-Mn are discussed

    Optical conductivity of amorphous Ta and beta-Ta films

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    Tantalum films evaporated in high vacuum onto liquid-nitrogen-cooled substrates had an amorphous structure that persisted even after warming to room temperature. The optical conductivity (as well as the dc conductivity) of the amorphous films differed significantly from that of the bcc films

    Technology transfer: Transportation

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    The successful application of aerospace technology to problems related to highways and rail and rapid transit systems is described with emphasis on the use of corrosion resistant paints, fire retardant materials, and law enforcement. Possible areas for the use of spinoff from NASA technology by the California State Department of Corrections are identified. These include drug detection, security and warning systems, and the transportation and storage of food. A communication system for emergency services is also described

    Nomenclature of the hydrotalcite supergroup: Natural layered double hydroxides

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    Layered double hydroxide (LDH) compounds are characterized by structures in which layers with a brucite-like structure carry a net positive charge, usually due to the partial substitution of trivalent octahedrally coordinated cations for divalent cations, giving a general layer formula [( M 2+ 1-x M 3+ x )(OH)2] x +. This positive charge is balanced by anions which are intercalated between the layers. Intercalated molecular water typically provides hydrogen bonding between the brucite layers. In addition to synthetic compounds, some of which have significant industrial applications, more than 40 mineral species conform to this description. Hydrotalcite, Mg6Al2(OH) 16[CO3]•4H2O, as the longest-known example, is the archetype of this supergroup of minerals. We review the history, chemistry, crystal structure, polytypic variation and status of all hydrotalcite-supergroup species reported to date. The dominant divalent cations, M 2+, that have been reported in hydrotalcite supergroup minerals are Mg, Ca, Mn, Fe, Ni, Cu and Zn; the dominant trivalent cations, M 3+, are Al, Mn, Fe, Co and Ni. The most common intercalated anions are (CO3)2-, (SO4)2- and Cl -; and OH-, S2- and [Sb(OH)6] - have also been reported. Some species contain intercalated cationic or neutral complexes such as [Na(H2O)6]+ or [MgSO4]0. We define eight groups within the supergroup on the basis of a combination of criteria. These are (1) the hydrotalcite group, with M 2+:M 3+ = 3:1 (layer spacing ∼7.8 Å); (2) the quintinite group, with M 2+:M 3+ = 2:1 (layer spacing ∼7.8 Å); (3) the fougèrite group, with M 2+ = Fe2+, M 3+ = Fe3+ in a range of ratios, and with O2- replacing OH- in the brucite module to maintain charge balance (layer spacing ∼7.8 Å); (4) the woodwardite group, with variable M 2+:M 3+ and interlayer [SO4] 2-, leading to an expanded layer spacing of ∼8.9 Å; (5) the cualstibite group, with interlayer [Sb(OH)6]- and a layer spacing of ∼9.7 Å; (6) the glaucocerinite group, with interlayer [SO4]2- as in the woodwardite group, and with additional interlayer H2O molecules that further expand the layer spacing to ∼11 Å; (7) the wermlandite group, with a layer spacing of ∼11 Å, in which cationic complexes occur with anions between the brucite-like layers; and (8) the hydrocalumite group, with M 2+ = Ca2+ and M 3+ = Al, which contains brucite-like layers in which the Ca:Al ratio is 2:1 and the large cation, Ca2+, is coordinated to a seventh ligand of 'interlayer' water. The principal mineral status changes are as follows. (1) The names manasseite, sjögrenite and barbertonite are discredited; these minerals are the 2H polytypes of hydrotalcite, pyroaurite and stichtite, respectively. Cyanophyllite is discredited as it is the 1M polytype of cualstibite. (2) The mineral formerly described as fougèrite has been found to be an intimate intergrowth of two phases with distinct Fe 2+:Fe3+ ratios. The phase with Fe2+:Fe 3+ = 2:1 retains the name fougèrite; that with Fe 2+:Fe3+ = 1:2 is defined as the new species trébeurdenite. (3) The new minerals omsite (IMA2012-025), Ni 2Fe3+(OH)6[Sb(OH)6], and mössbauerite (IMA2012-049), Fe3+ 6O 4(OH)8[CO3]•3H2O, which are both in the hydrotalcite supergroup are included in the discussion. (4) Jamborite, carrboydite, zincaluminite, motukoreaite, natroglaucocerinite, brugnatellite and muskoxite are identified as questionable species which need further investigation in order to verify their structure and composition. (5) The ranges of compositions currently ascribed to motukoreaite and muskoxite may each represent more than one species. The same applies to the approved species hydrowoodwardite and hydrocalumite. (6) Several unnamed minerals have been reported which are likely to represent additional species within the supergroup. This report has been approved by the Commission on New Minerals, Nomenclature and Classification (CNMNC) of the International Mineralogical Association, voting proposal 12-B. We also propose a compact notation for identifying synthetic LDH phases, for use by chemists as a preferred alternative to the current widespread misuse of mineral names. © 2012 Mineralogical Society.Fil: Mills, S.J.. Museum Victoria; AustraliaFil: Christy, A.G.. Australian National University. Centre for Advanced Microscopy; AustraliaFil: Génin, J. M. R.. CNRS-Université de Lorraine; FranciaFil: Kameda, T.. Tohoku University. Graduate School of Environmental Studies; JapónFil: Colombo, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentin

    Climate dynamics experiments using a GCM simulations

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    The study of surface-atmosphere interactions has begun with studies of the effect of altering the ocean and land boundaries. A ten year simulation of global climate using observed sea surface temperature anomalies has begun using the NCAR Community Climate Model (CCM1). The results for low resolution (R15) were computed for the first 8 years of the simulation and compared with the observed surface temperatures and the MSU (Microwave Sounding Unit) observations of tropospheric temperature. A simulation at higher resolution (T42) was done to ascertain the effect of interactive soil hydrology on the system response to an El Nino sea surface temperature perturbation. Initial analysis of this simulations was completed

    Lone Star Productions

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    Lone Star Productions (LSP) is a concert promotions business that was started in 1981 by Bill Oldman. Since 1986, this company has been the exclusive provider of concert promotion materials for 75% of the top grossing national tours. In 1997, Bill Oldman sold the company to a group of investors headed by Mike Sims. With a background in banking and investments, Sims took over a LSP’s president. Bill Oldman remained as the Chief Executive Officer of the company. Lone Star Productions’ business encompasses several segments, including concert promotions, audio and video production, production staffing, video editing, web site development, and equipment and suite rental. Currently, concert promotions account for 90% of the company’s revenue. Efforts to build business in the areas other than concert promotion have been mildly successful, but LSP considers the further development of these business areas to be critical to the long-term profitability and financial stability of the company, LSP is currently considering buying the largest video production company in the Dallas, Texas area.(Contact author for a copy of the complete report.)Small Busn. Mgmt

    Global water cycle

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    The primary objective is to determine the scope and interactions of the global water cycle with all components of the Earth system and to understand how it stimulates and regulates changes on both global and regional scales. The following subject areas are covered: (1) water vapor variability; (2) multi-phase water analysis; (3) diabatic heating; (4) MSU (Microwave Sounding Unit) temperature analysis; (5) Optimal precipitation and streamflow analysis; (6) CCM (Community Climate Model) hydrological cycle; (7) CCM1 climate sensitivity to lower boundary forcing; and (8) mesoscale modeling of atmosphere/surface interaction

    Uncertainties in determining parton distributions at large x

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    We critically examine uncertainties in parton distribution functions (PDFs) at large x arising from nuclear effects in deuterium F2 structure function data. Within a global PDF analysis, we assess the impact on the PDFs from uncertainties in the deuteron wave function at short distances and nucleon off-shell effects, the use of relativistic kinematics, as well as the use of less a restrictive parametrization of the d/u ratio. We find that in particular the d-quark and gluon PDFs vary significantly with the choice of nuclear model. We highlight the impact of these uncertainties on the determination of the neutron structure function, and on W boson production and parton luminosity at the Tevatron and the LHC. Finally, we discuss prospects for new measurements sensitive to the d-quark and gluon distributions but insensitive to nuclear corrections.Comment: 37 pages, 13 figures. Final published versio

    New parton distributions from large-x and low-Q^2 data

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    We report results of a new global next-to-leading order fit of parton distribution functions in which cuts on W and Q are relaxed, thereby including more data at high values of x. Effects of target mass corrections (TMCs), higher twist contributions, and nuclear corrections for deuterium data are significant in the large-x region. The leading twist parton distributions are found to be stable to TMC model variations as long as higher twist contributions are also included. The behavior of the d quark as x-->1 is particularly sensitive to the deuterium corrections, and using realistic nuclear smearing models the d-quark distribution at large x is found to be softer than in previous fits performed with more restrictive cuts.Comment: 31 pages, 8 figures. Minor corrections. References added. To appear in Phys.Rev.

    Star Formation in the Field and Clusters of NGC 5253

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    We investigate the star formation history of both the bright star clusters and the diffuse `field star' population in the dwarf starburst galaxy NGC 5253 using STIS longslit ultraviolet spectroscopy. Our slit covers a physical area of 370 x 1.6 pc and includes 8 apparent clusters and several inter-cluster regions of diffuse light which we take to be the field. The diffuse light spectrum lacks the strong O-star wind features which are clearly visible in spectra of the brightest clusters. This discrepancy provides compelling evidence that the diffuse light is not reflected light from nearby clusters, but originates in a UV-bright field star population, and it raises the issue of whether the star formation process may be operating differently in the field than in clusters. We compare our spectra to STARBURST99 evolutionary synthesis models which incorporate a new low metallicity atlas of O-star spectra. We favor a scenario which accounts for the paucity of O-stars in the field without requiring the field to have a different IMF than the clusters: stellar clusters form continuously and then dissolve on ~10 Myr timescales and disperse their remaining stars into the field. We consider the probable contribution of an O-star deficient field population to the spatially unresolved spectra of high redshift galaxies. (Abridged)Comment: 26 pages, 10 figures, accepted for publication in Ap
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